González Abad, Gonzalo, Liu, X., Chance, Kelly V., Wang, H., Kurosu, T. P., and Suleiman, R. 2014. "Updated SAO OMI formaldehyde retrieval." Atmospheric Measurement Techniques Discussions 7:1-31. https://doi.org/10.5194/amtd-7-1-2014
We present and discuss the Smithsonian Astrophysical Observatory (SAO) formaldehyde (H2CO) retrieval algorithm for the Ozone Monitoring Instrument (OMI) which is the operational retrieval for NASA OMI H2CO. The version of the algorithm described here includes relevant changes with respect to the operational one, including differences in the reference spectra for H2CO, the fit of O2-O2 collisional complex, updates in the high resolution solar reference spectrum, the use of a model reference sector over the remote Pacific Ocean to normalize the retrievals, an updated Air Mass Factor (AMF) calculation scheme, and the inclusion of scattering weights and vertical H2CO profile in the level 2 products. The theoretical basis of the retrieval is discussed in detail. Typical values for retrieved vertical columns are between 4 × 1015 and 4 × 1016 molecules cm-2 with typical fitting uncertainties ranging between 40% and 100%. In high concentration regions the errors are usually reduced to 30%. The detection limit is estimated at 3 × 1015 molecules cm-2. These updated retrievals are compared with previous ones.